In this paper, a fast fluidized bed reactor was proposed for pyridine synthesis. Fluidization or suspension can be carried out on a large range of material densities and particle sizes. Fluidization is a method of mixing fuel and air in a specific proportion, for obtaining combustion. Fluidized beds operate by balancing the downward gravity forces of the weight of the particles in the charge with the upward forces created by high gas flow. In this type of reactor, a fluid gas or liquid is passed through a solid granular material usually a catalyst possibly shaped as tiny spheres at high enough speeds to suspend the solid and cause it to behave as though it were a fluid. We have such a reactor in our laboratory which could be used to study the operating characteristics of the bed. The fluidizedbed reactor has the ability to process large volumes of fluid.
A fluidized bed is formed when a fixed mass of solid particulate is situated in appropriate conditions to support a solidfluid mixture uniformity to behave as a fluid. The carbon conversion efficiency of the hotmodel fluidized bed gasifier unit is found out to be 81. Gas fluidized beds are characterized by the bubbles which form at superficial gas velocities only slightly higher than that required to just fluidize the particles. A schematic diagram of a typical fluidized bed membrane reactor is shown in fig 1. The name fluidized bed reactors fbr is a generic term and encompasses a variety of engineering systems including chemical reactors, combustors, gasifiers, calcifiers, driers, etc.
The common characteristic of the fbr class of engineering systems is the presence of the solid particles that are carried by the fluid and exist in a. Fluidizedbed gasifiers may differ in ash conditions dry or agglomeratedslagging and in design configurations for improving char use. Preheated steam and methane are premixed and then fed to the reactor where the following principal reforming reactions take place. Fluidization occurs when small solid particles are suspended in an upward. Fluidized bed membrane reactor fluidized bed membrane reactor is a combination of chemical reactor and a membrane. A fluidized bed reactor was designed and constructed for practical demonstration of the fluidization of solid particles at different fluid flow rates. These reactors generally behave in a manner intermediate between cstrs and pbrs. A fluidized bed may be defined as the bed of solid particles behaving as a fluid. Four kilograms of catalyst with particles size of 100. Gassolid conversion in fluidised bed reactors core. Fluidizedbed reactor systems for chemicallooping combustion with inherent separation of co 2 eva johansson department of energy and environment division of energy technology chalmers university of technology abstract in chemicallooping combustion clc a gaseous fuel can be burnt with inherent separation of carbon dioxide.
They consist of a bed of immobilised enzyme which is fluidised by the rapid upwards flow of the substrate stream alone or in combination with a gas or secondary liquid stream, either of which may be inert or contain material relevant to the reaction. When the fluid velocity is increased to a certain value. Fluidized beds typically are more complex to design, build, and operate than other types of reactors, such as packedbed and stirredtank reactors. A fluidized bed is a physical phenomenon occurring when a quantity of a solid particulate substance usually present in a holding vessel is placed under appropriate conditions to cause a solidfluid mixture to behave as a fluid. Investigation of pyridine synthesis in a fast fluidized. Fluidized bed characteristics our pilot plant group wishes to insert a fluidized bed reactor in one of the tail gas streams from their new pilot plant. Experiment results show that the yields of pyridine and 3picoline decrease while the selectivity of pyridine over 3picoline is increased. Fcc process is very complex and require good understanding of many factors such as kinetic models, reaction kinetic, fluid dynamics, feed and catalyst effects, temperature, residence time in the riser, catalyst deactivation and its regeneration. This is usually achieved by the introduction of pressurized fluid through the particulate medium. A result of the mixing is excellent temperature stability and increased masstransfer and reaction rates. Fluidization or fluidisation is a process similar to liquefaction whereby a granular material is converted from a static solidlike state to a dynamic fluidlike state. This process occurs when a fluid liquid or gas is passed up through the granular material.
Fluidized bed reactors are capable of handling large amounts of feed and catalyst. Stationary or bubbling bed sb circulating fluidized beds cfb vibratory fluidized beds vfb. A model was proposed to predict the performance of the fast fluidized. Due to the large exothermic of the ocm reaction, a fluidized bed reactor enables an almost isothermal reactor performance in ocm and was therefore the first investigated reactor type. The fluidized bed reactor page university of washington. The equipment works on a principle of fluidization of the feed materials. Fluidized bed combustion types and advantages electrical4u. Fluidized bed dryer also called fluid bed dryer is a kind of equipment used extensively in the pharmaceutical industries to reduce moisture content of pharmaceutical powder and granules.
For three different catalytic fluidized bed reactor models, two models presented by werther and a model presented by van deemter, the region of safe and unique operation for a. In this work, a numerical investigation is conducted using the computational particle fluid. Conventional fluidized bed reactor figure 2 illustrates the performance of the catalytic fluidized bed reactor without membranes at different temperatures and at different excess velocities i. Fluidized beds are prone to erosion and particle attrition caused by the moving particles. Different gassolid flow regimes for wood and glass particles of groups a, b, and d of geldarts classification are. This webinar explores the fundamentals of fluidization. Fluidized bed reactors parr fluidized bed reactors are used extensively in the chemical process industries. Fixed bed fixed bed reactor is a cylindrical tube, randomly filled with catalyst particles, which may be spheres or cylindrical pellets. The effects of different gassolid flow regimes on the operating conditions and heat transfer rate between the hot air and two types of low and high. Understanding the gasification and combustion rates of biomass char is an. For the catalytic cracking of petroleum naphthas to form gasoline blends, for example, the virtues of the fluidizedbed reactor drove its competitors from the market. When a gas flow is introduced through the bottom of a bed of solid particles, it will move upwards through the bed via the empty. The effect of parameters on the performance of a fluidized.
A dual circulating fluidized bed reactor for chemical looping combustion of coal has the advantage of flexible regulation on oxygen carrier circulation, but there is always part of unconverted coal char escaping from the fuel reactor fr, reducing the carbon capture efficiency of the whole unit. This reactor provides easy loading and removal of catalyst. Numerical study of different gassolid flow regimes. Safe design and operation of fluidizedbed reactors. University of groningen particle transport in fluidized. Fluidized bed reactor basic mechanism, mass transfer in fluidized beds, reaction behaviour in a fluidized bed, mole balance on the bubble, the cloud, and the slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising.
The heattransfer rate in a fluidized bed can be five to ten times greater than that in a packedbed reactor. This allows for extensive mixing in all directions. Fluidized beds are used for several purposes, such as fluidized bed reactors types of chemical reactors, fluid catalytic cracking, fluidized bed combustion, heat or mass transfer or interface modification, such as. Fluidized beds typically are more complex to design, build, and operate than other types of reactors, such as packed bed and stirredtank reactors. The high heat transfer rates from fluidized sand cause rapid heating of biomass particles and some ablation by.
Application of different types of bioreactors in bioprocesses. This is a reasonable approximation of a fluidized bed, but there are many more complicated models that can be seen in the above figure. Analysis of fluidizedbed and fluidizedbedmembrane reactor. Modeling of a nickelbased fluidized bed membrane reactor for. Fluidized beds are a very important and common process technology used for everything from roasting coffee beans and drying agricultural grains to fluid catalytic cracking and pharmaceutical granulation. As being seen, the advantages of fluidizedbed reactor over other types of reactors, is based all on great heat transfer because of fluid behaviour of the whole bed. For other topics on fluidization, see fluidized bed technology, fluidized bed combustion and fluidization. Fluidized bed device that can be used to carry out a variety of multiphase chemical reactions. Emphasis is placed on correct reactor design which, as will be shown, reduces to choosing the shape of the reactor, the method of aeration and the type, size, density and size distribution of the particles in the bed. However, to ensure that a stable fluid bed is maintained, the range of particle sizes that may be used in any one reactor must be within an order of magnitude, e. Consequently, a detailed design of a fluidized bed reactor that would allow flexible operation at high temperature and high pressure at several gas velocities will be conducted in order to serve for the future development of new hydrodynamic models.
In fluidization process, hot air is introduced at high. Ammonia oxidation takes place in a bubbling fluidized bed reactor at 1. Fluidized bed reactor fbr from wikipedia an ose fbr should be built of discrete components that are integrated rather than dependent on one another, so a machine can be assembled into configurations for applications that use different pieces of equipment. Dual fluidized bed reactor system for gas, heat and energy production duration.
Current applications for fluidized bed reactors fbrs are everywhere in the process industries. It operates on the principal that when an evenly distributed air is passed upward through a finely divided bed of solid particles at low velocity, the particles remain undisturbed, but if the velocity of air flow is. They find broad use in the petroleum and petrochemical industries, as well as numerous chemical industries. When talking about a fluidized bed, mostly one refers to a bubbling fluidized bed type as shown in fig. The distinguishing feature of a fluidized bed reactor is that the bed of solid particles or catalyst is supported by an up flow of gas. Likewise, the successful application of fluidized bed reactors to highly. Moving particles, especially small particles, can transport heat much more efficiently than gas alone. Inside the fluidized bed itself, the particles are highly mobile and this results in relatively uniform bed temperatures and good control over reactions in. In this type of reactor, a fluid gas or liquid is passed through a granular solid material usually a catalyst at high enough velocities to suspend the solid and cause it to behave as it were a liquid. Numerical investigation on the improvement of carbon. These pages were constructed to convey the importance of fluidized bed reactors fbrs in todays petroleum and chemical process industries. Fluidized bed reactors are heterogeneous catalytic reactors in which the mass of catalyst is fluidized.
This results in the medium then having many properties and. They found that the amount of products is affected by ncg. Fluidized beds are classified by their flow behavior. Fluidized catalytic cracking riser reactor operating. Even for the most extreme exothermic reactions, a fluidized bed can maintain an isothermal profile within a few degrees. A fluidized bed reactor fbr is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. Experimental method and setup for laboratory fluidized bed. Pdf application of different types of bioreactors in. The present model allows analysis of different types of ncgsr in a generalised way, handling catalytic reactions as a particular, simpler, case. Bubbling fluidized bed reactor bubbling fluidized beds, biomass particles are introduced into a bed of hot sand fluidized by a recirculated product gas. A fluidized bed reactor fbr is a type of reactor device that can be used to carry out a variety of.
859 791 102 523 463 1262 1004 1474 1128 3 1341 1410 627 665 1443 1000 1528 782 1342 215 1405 573 1127 256 1495 1139 597 454 659 364 662 913 501 1042 1283 635 603 37 554 261 390 1461 140